ContentsPage
4 Principle
5 Reagents
6 Apparatus
7 Conditioning and testing atmosphere
8 Sampling and pre-treatment of laboratory test sample
8.1 Sampling
8.2 Pre-treatment of laboratory test sample
9 Procedure
9.1 General instructions
9.1.1 Handling
9.1.2 Drying
9.1.3 Drying of test specimens
9.1.4 Drying of crucible and residue
9.1.5 Cooling
9.1.6 Weighing
9.2 Testing execution
10 Calculation and expression of results
11 Precision of the methods
12 Test report
Annex A (normative) Methods for the removal of non-fibrous matter
Annex B (normative) Method of quantitative analysis by manual separation
Foreword
ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.
The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular, the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see
www.iso.org/directives).
Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see
www.iso.org/patents).
Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.
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www.iso.org/iso/foreword.html.
This document was prepared by Technical Committee ISO/TC 38, Textiles, in collaboration with the European Committee for Standardization (CEN) Technical Committee CEN/TC 248, Textile and textile products, in accordance with the Agreement on technical cooperation between ISO and CEN (Vienna Agreement).
This second edition cancels and replaces the first edition (ISO 1833-1:2006), which has been technically revised. It also incorporates the Technical Corrigendum ISO 1833-1:2006/Cor 1:2009.
The main changes compared to the previous edition are as follows:
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Introduction, A.2 and bibliography: a reference to ISO/TR 11827 regarding the fibre identification has been added;
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Clause 2: normative references have been added;
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Clause 4: references to ISO 2076 and ISO 6938 have been added for the use of the generic names in the ISO 1833 series;
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Clause 5: warning sentences and reference to grade 3 water have been introduced;
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Clause 6: stoppered weighing bottles have been added;
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8.2: all pretreatments have been described in Annex A (including pretreatment with light petroleum) a requirement for reporting if any pretreatment is carried out [see Clause 12, e)] has been introduced;
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9.1.1: instructions for handling have been added;
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9.1.2: instructions for short drying period have been added;
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9.1.6 (former 9.1.5): a note has been removed;
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9.2: a requirement regarding the number of test specimens has been added;
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Clause 10: deletion of former 10.3 (consideration of only percentage additions for moisture, case included in the new 10.3 covering percentage additions for moisture and non-fibrous matter, and/or percentage losses of fibrous matter by pre-treatment);
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10.3: additional instructions in case of calculated percentage greater than 100 % have been given;
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Annexes A and B have been changed to normative;
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Table A.1 and concerned subclauses: additional cases regarding elastane (see A.5.1.2), elastolefin (see A.5.1.3), bast fibres (see A.5.25) have been introduced;
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B.8.1 and B.8.2: a requirement regarding the number of test specimens has been added.
A list of all parts in the ISO 1833 series can be found on the ISO website.
Any feedback or questions on this document should be directed to the user’s national standards body. A complete listing of these bodies can be found at
www.iso.org/members.html.
Introduction
Methods for the quantitative analysis of fibre mixtures are based on two main processes, the manual separation and the chemical separation of fibres.
It is preferable to use the method of manual separation, which is given in Annex B, whenever possible since it generally gives more accurate results than the chemical method. It can be used for all textiles whose component fibres do not form an intimate mixture, for example in the case of yarns composed of several elements each of which is made up of only one type of fibre, or woven fabrics in which the fibre of the warp is of a different kind to that of the weft, or knitted fabrics capable of being unravelled made up of yarns of different types.
In general, the methods described in the different parts of ISO 1833 are based on the selective dissolution of an individual component. After the removal of a component, the insoluble residue is weighed, and the proportion of soluble component is calculated from the loss in mass. This document gives the information which is common to the analyses, by this method, of all fibre mixtures, whatever their composition. This information is intended to be used in conjunction with the other parts of ISO 1833; these parts contain the detailed procedures applicable to particular fibre mixtures. Where, occasionally, an analysis is based on a principle other than selective dissolution, full details are given in the appropriate part.
Mixtures of fibres obtained during processing and, to a lesser extent, in finished textiles can contain non-fibrous matter, such as fats, waxes or dressings, or water-soluble matter, either occurring naturally or added to facilitate processing. Non-fibrous matters are removed before analysis.
A method of pre-treatment for removing oils, fats, waxes and water-soluble matter is given in Annex A.
Dye in dyed fibres is considered to be an integral part of the fibre and is not removed.
In addition, textiles can contain resins or other matter added to bond the fibres together or to confer special properties, such as water-repellence or crease-resistance. Such matter, including dyestuffs in exceptional cases, can interfere with the action of the reagent on the soluble component and/or it can be partially or completely removed by the reagent. This type of added matter can also cause errors and are removed before the sample is analysed. If it is impossible to remove such added matter, the methods of analysis are no longer applicable.
Most textile fibres contain water, the amount depending on the type of fibre and on the relative humidity of the surrounding air. Analyses are conducted on the basis of dry mass, and a procedure for determining the dry mass of test specimens and residues is given in this document.
The result is therefore obtained on the basis of clean, dry fibres.
Provision is made for recalculating the result on the basis of
a)
agreed moisture regain
NOTEThe agreed moisture regain of each fibre is specified in some regional legislation or after agreement between interested parties.
b)
agreed moisture regain and also for
1)
fibrous matter removed in the pre-treatment, and
2)
non-fibrous matter (for example, fibre dressing, processing oil, or size) that can be properly regarded as part of the fibre as an article of commerce.
In some methods, the insoluble component of a mixture can be partially dissolved in the reagent used to dissolve the soluble component. Where possible, the reagents that have been chosen are those that have little or no effect on the insoluble fibres. If loss in mass is known to occur during the analysis, the result is corrected; correction factors for this purpose are given. These correction factors have been determined in several laboratories by treating, in the appropriate reagent as specified in the method of analysis, fibres cleaned by the pre-treatment.
These correction factors apply only to undegraded fibres, and different correction factors might be necessary if the fibres have been degraded during processing.
The procedures given apply to single determinations; at least two determinations on separate test specimens are made, both in the case of manual separation and in the case of chemical separation, but more may be carried out if desired.
Before proceeding with any quantitative analysis, it is assumed that all the fibres present in the mixture have been identified. For this purpose, ISO/TR 11827 may be used.
For confirmation, unless it is technically impossible, it is recommended that use be made of alternative procedures whereby the component that would be the residue in the standard method is dissolved out first.